A. Cuoci, A. Frassoldati, T. Faravelli, H. F. Jin, Y. Z. Wang, K. W. Zhang, P. Glarborg and F. Qi (2013) Experimental and detailed kinetic modeling study of PAH formation in laminar co-flow methane diffusion flames. Journal/Proceedings Of the Combustion Institute 34 1811-1818. [In English]
Web link: http://dx.doi.org/10.1016/j.proci.2012.05.085
Keywords: Methane oxidation, PAH formation, Detailed kinetics, Co-flow diffusion, flame, POLYCYCLIC AROMATIC-HYDROCARBONS, PREMIXED METHANE, SOOT FORMATION, NONPREMIXED FLAMES, FORMATION PATHWAYS, OXIDATION, COMBUSTION, DECOMPOSITION, PHOTOIONIZATION, PRECURSORS
Abstract: In the present paper, synchrotron VUV photoionization mass spectrometry is used to study the detailed chemistry of co-flow methane diffusion flames with different dilution ratios. The experimental results constitute a comprehensive characterization of species important for PAH and soot formation under conditions that resemble those of practical flames. In addition to the main C-1/C-2 species, unsaturated C-3 (C3H2, C3H3, aC(3)H(4), pC(3)H(4)), C-4 (C4H2, C4H4, C4H6), and C-6 (C6H2) species as well as first aromatics (C6H6, C7H8, C10H8, C12H8) are detected. The laminar, co-flow flames were simulated using an original CFD code based on the operator-splitting technique, specifically conceived to handle large kinetic mechanisms. The detailed kinetic modeling was effectively used to describe and analyze the fuel consumption and the formation of PAH. Experimental measurements and numerical predictions were found to be in satisfactory agreement and showed the relative importance of the C-2 and C-3 mechanisms in the formation of the first aromatics. (C) 2012 The Combustion Institute. Published by Elsevier Inc. All rights reserved.